Using PS, how can I get a list of ALL email addresses on our Exchange Server(2010) remotely?
if you are inside the network, just use a implicit PSRemote session to your Exchange server, which proxies the Exchange cmdlets to your local host for the session, then just run the normal Exchange cmdlets to get what you are after. Get-Mailbox for example.
Windows PowerShell: Implicit Remoting'technet.microsoft.com/en-us/library/ff720181.aspx
Connect to Exchange servers using remote PowerShell'docs.microsoft.com/en-us/powershell/exchange/exchange-server/connect-to-exchange-servers-using-remote-powershell?view=exchange-ps'
Create a new implicit remoting session on a remote Exchange 2010 server'gallery.technet.microsoft.com/office/Create-a-new-implicit-5fdafe45
Remote PowerShell in Exchange 2013'blogs.technet.microsoft.com/nathanscott/2015/06/14/remote-powershell-in-exchange-2013
Exchange Server 2013 PowerShell Implicit Remoting over the Internet using IIS ARR as the Reverse Proxy'social.technet.microsoft.com/wiki/contents/articles/31066.exchange-server-2013-powershell-implicit-remoting-over-the-internet-using-iis-arr-as-the-reverse-proxy.aspx'