Powershell.exe.config

I have seen many references to this config file for adding support for additional version of .NET.  This got me thinking about further possibilities for the config file.  Unfortunately, in my searches, I have not been able to find much about this possibility.  If you were to add additional configuration options base upon the configuration file schema for .NET framework (http://msdn.microsoft.com/en-us/library/1fk1t1t0), will it work?  For example, if you were to use the mailSettings element (http://msdn.microsoft.com/en-us/library/w355a94k.aspx), would it work?

I am not looking at using the mailSettings element, but I am curious to know if the options presented in the configuration file schema will work.

 

Thanks!

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